## Abstract **Summary:** A detailed investigation of chain transfer to polymer during free radical ringโopening polymerization of the eightโmembered disulfide monomer 2โmethylโ7โmethyleneโ1,5โdithiacyclooctane (MDTO) is presented. It has been shown that extensive chain transfer to polymer occurs in
Chain length dependency of head-to-head addition in the radical polymerization of allyl monomers
โ Scribed by Akira Matsumoto; Manabu Kikuta; Masayoshi Oiwa
- Book ID
- 105336154
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1986
- Tongue
- English
- Weight
- 256 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0887-6258
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Radical polymerizations of triallyl isocyanurate (TALC) and its isomer triallyl cyanurate (TAC) were conducted in benzene at 60 ยฐ. In the polymerization of TALC, gelation occurred quite early and the primary chain length was quite high compared with that for TAC. Both TAlC and TAC were copolymerized
A~traet A numeric solution is developed for a kinetic scheme involving chain length dependent termination (by disproportionation) and chain transfer on the basis of the harmonic and the geometric mean approximation for the two radicals involved in the termination process. In addition, solutions in t