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Chain Folding and Diffusion in Monodisperse Long n-Alkanes by Solid-State NMR

โœ Scribed by Grasso, Giuseppe; Titman, Jeremy J.


Book ID
111676411
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
704 KB
Volume
42
Category
Article
ISSN
0024-9297

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A set of new peaks in the high-resolution solid-state 13C NMR spectrum of y-irradiated crystalline n-alkanes have been assigned to intact alkanes in the glassy region formed by corruption of the crystal structure. The saturation recovery curve for the interior methylene carbon showed that the flexib