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Chain-extended crystallization of polyethylene: effect of sample thickness

✍ Scribed by D.C. Bassett; B.A. Khalifa

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 979 KB
Volume: 14
Category: Article
ISSN: 0032-3861
DOI: 10.1016/0032-3861(73)90027-x

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## Abstract ^13^C solid‐state exchange NMR is applied to study the influence of morphology on chain diffusion between crystalline and noncrystalline regions in ultrahigh molecular weight linear polyethylene (PE). Lamellar‐doubling reduces the exchange rate by a factor of two indicating that the cha