𝔖 Bobbio Scriptorium

✦ LIBER ✦

C−H versus Ir−X (X = H, Cl) Reactivity in a Tropylium PCP Pincer Iridium Complex 1

✍ Scribed by Winter, Angelika M.; Eichele, Klaus; Mack, Hans-Georg; Kaska, William C.; Mayer, Hermann A.

Book ID: 127294899
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 157 KB
Volume: 24
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om049289+

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Novel Amido-Bridged Dinuclear Iridium(II

Novel Amido-Bridged Dinuclear Iridium(III) and Iridium(II) Complexes. Synthesis and Characterization of [Cp*Ir(μ 2 -NHC 6 H 4 R- p ) 3 IrCp*]Cl (Cp* = η 5 -C 5 Me 5 ; R = Me, H, Cl, CF 3 ), [Cp*Ir{(μ 2 -NH) 2 C 10 H 6 -1,8}(μ 2 -X)IrCp*]X (X = Cl, Br), Cp*Ir{(μ 2 -NH) 2 C 10 H 6 -1,8}IrCp*, and [Cp*Ir{(μ 2 -NH) 2 C 10 H 6 -1,8}(μ 2 -H)IrCp*]O 2 CCF 3

✍ Matsuzaka, Hiroyuki; Ariga, Ko; Kase, Hiroshi; Kamura, Teruo; Kondo, Mitsuru; Ki 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 201 KB

Stereochemical and Electronic Control of

Stereochemical and Electronic Control of Functionalized Tripodal Phosphines. Reactivity of the Adamantane-Type Ir(tripod)(CO)Cl (tripod = cis,cis -1,3,5-(PPh 2 ) 3 -1,3,5-X 3 C 6 H 6 ; X = H, COOMe, CN) Complexes toward H + , H 2 , CO, and C 2 H 41

✍ Stössel, Philipp; Heins, Wolfgang; Mayer, Hermann A.; Fawzi, Riad; Steimann, Man 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 465 KB

Synthesis and molecular structure of a n

Synthesis and molecular structure of a new family of iridium-(III) and rhodium(III) complexes: [(η5-Me5C5)Ir(LL)X]+ and [(η5-Me5C5)Rh(LL)Cl]+; LL = 2,2′-bipyridine or 1,10-phenanthroline; X = Cl or H. Single crystal structures of [(η5-Me5C5)Ir(bpy)Cl]Cl and [(η5-Me5C5)Rh(phen)Cl]ClO4

✍ Marie-Thérèse Youinou; Raymond Ziessel 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 828 KB

Evidence for a strong similarity in conf

Evidence for a strong similarity in conformational and phosphorus-31 NMR parameters between two series of trans-[(tert-C4H9)2PX]2M(CO)Cl complexes [M = Rh(I), Ir(I); X = H, CH3, C2H5, n-C4H9, C6H5]

✍ Bushweller, C. Hackett; Rithner, Christopher D.; Butcher, David J. 📂 Article 📅 1984 🏛 American Chemical Society 🌐 English ⚖ 472 KB

Reaction Mechanism and Structure–Reactiv

Reaction Mechanism and Structure–Reactivity Relationships in the Stereospecific 1,4-Polymerization of Butadiene Catalyzed by Neutral Dimeric Allylnickel(II) Halides [Ni(C3H5)X]2 (X−=Cl−, Br−, I−): A Comprehensive Density Functional Theory Study

✍ Sven Tobisch; Rudolf Taube 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 281 KB

The nature of the phosphorus-metal bond

The nature of the phosphorus-metal bond in triphenylphosphine—transition metal complexes (Pd[P(C6H5)3]4, Rh(CO)Cl[P(C6H5)3]2 and Ir(CO)Cl[P(C6H5)3]2. A direct determination of the importance of P3d and PC σ∗ orbitals in ‘back-bonding’ by X-ray emission spectroscopy

✍ Caroline Bourg; Stuart Gamblin; David S Urch 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 719 KB