C—H Insertion Reactions, Cycloadditions, and Ylide Formation of Diazo Compounds
✍ Scribed by Huw M. L. Davies
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 7 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Pyrolysis of the relatively stable, solid complexes of cyclomaltoheptaose (/3cyclodextrin) with phenyldiazomethane, 1-diazo-1-phenylethane, and diazo-(diphenyl)methane results in degradation of the labile guests. The host matrix exerts "reaction-vessel" and "shape-selectivity" effects upon the reac
Diazoamides la and lb were prepared from 2-(O-allyl)-and 2-(S-allyl) anilines 2 respectively. Copper(II) catalysed decomposition of 1 resulted in formation of benzofused heterocycles 7 by [2,3]-rearrangement of the intermediate ylide. Rhodium(II) perfluorbutyramide catalysed reaction, however, gave