Intramolecular CH activation by dicatio
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Antek G. Wong-Foy; Lawrence M. Henling; Mike Day; Jay A. Labinger; John E. Berca
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Article
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2002
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Elsevier Science
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English
⚖ 240 KB
The dicationic complexes [(ArN=C(Me)-C(Me)=NAr)Pt(solv) 2 ]X 2 , (Ar = 2,6-(CH 3 ) 2 C 6 H 3 ; 5a: -, PF 6 -, SbF 6 -) were synthesized from the corresponding Pt dichlorides with two equivalents of AgX. The reactions of 5a with 1-phenylpyrazole, 2-phenylpyridine, 2-vinylpyridine, and 2-(2-thienyl)p