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C−H Bond Activation by Dicationic Platinum(II) Complexes

✍ Scribed by Driver, Tom G.; Williams, Travis J.; Labinger, Jay A.; Bercaw, John E.


Book ID
127079238
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
240 KB
Volume
26
Category
Article
ISSN
0276-7333

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Intramolecular CH activation by dicatio
✍ Antek G. Wong-Foy; Lawrence M. Henling; Mike Day; Jay A. Labinger; John E. Berca 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 240 KB

The dicationic complexes [(ArN=C(Me)-C(Me)=NAr)Pt(solv) 2 ]X 2 , (Ar = 2,6-(CH 3 ) 2 C 6 H 3 ; 5a: -, PF 6 -, SbF 6 -) were synthesized from the corresponding Pt dichlorides with two equivalents of AgX. The reactions of 5a with 1-phenylpyrazole, 2-phenylpyridine, 2-vinylpyridine, and 2-(2-thienyl)p