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C−H Bond Activation by Cationic Platinum(II) Complexes: Ligand Electronic and Steric Effects

✍ Scribed by Zhong, H. Annita; Labinger, Jay A.; Bercaw, John E.


Book ID
118045200
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
373 KB
Volume
124
Category
Article
ISSN
0002-7863

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Steric and electronic effects on 195Pt N
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## Abstract Platinum‐195 chemical shift measurements for __cis__‐PtCl~2~(PCy~3~)~2~ and __trans__‐PtXCl(PCy~3~)~2~ (X = H, Cl, SnCl~2~Ph and SnCl~3~) in methylene chloride solution are reported. A comparison of these shifts with those from analogous complexes containing less bulky phosphine ligands