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Cerium(IV) Ammonium Nitrate (CAN) Catalyzed Aza-Michael Addition of Amines to α,β-Unsaturated Electrophiles.

✍ Scribed by Zheng Duan; Xuejie Xuan; Ting Li; Chenfei Yang; Yangjie Wu

Publisher
John Wiley and Sons
Year
2006
Weight
27 KB
Volume
37
Category
Article
ISSN
0931-7597

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Transition-Metal-Based Lewis Acid Cataly
Transition-Metal-Based Lewis Acid Catalysis of Aza-Type Michael Additions of Amines to α,β-Unsaturated Electrophiles in Water
✍ Li-Wen Xu; Lyi Li; Chun-Gu Xia 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 German ⚖ 69 KB

Several transition-metal-based Lewis acid catalysts, especially FeCl 3 ¥ 7 H 2 O, CrCl 3 ¥ 6 H 2 O, and SnCl 4 ¥ 4 H 2 O, were shown to be highly effective for aza-type Michael reactions between electrophilic a,b-unsaturated compounds and both aliphatic and aromatic amines in aqueous solution. Advan