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Cerium(III) ion catalysis in the oxalic acid-bromate reaction: Anomalous kinetic behavior of oxalic acid

✍ Scribed by Sanjeeva Reddy, Ch. ;Sundaram, E. V.


Book ID
112686598
Publisher
Springer
Year
1988
Tongue
English
Weight
235 KB
Volume
36
Category
Article
ISSN
0133-1736

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Kinetics of the manganese(III)-oxalate r
✍ L'ubica AdamčíkovΓ‘; Adriana KrΓ­ΕΎovΓ‘; Ivan Valent πŸ“‚ Article πŸ“… 1993 πŸ› Springer 🌐 English βš– 286 KB

The kinetics of the reaction of manganese(III) with oxalic acid (OA) has been studied in H2SO 4 solutions. Under the experimental conditions of 6 x 10 -3 < [OA]o < 0.4mol dm-3 and [H2SO4]o >~ 0.2 mol dm-3 the observed pseudofirst order rate constant kob ~ follows the expression where kl, k2 and K 2