𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cerium(III) chloride mediated addition of Grignard reagents to nitroalkanes: synthesis of N,N-disubstituted hydroxylamines

✍ Scribed by Bartoli, Giuseppe; Marcantoni, Enrico; Petrini, Marino

Book ID
118208434
Publisher
The Royal Society of Chemistry
Year
1993
Tongue
English
Weight
220 KB
Volume
18
Category
Article
ISSN
0022-4936

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Encyclopedia of Reagents for Organic Syn
Encyclopedia of Reagents for Organic Synthesis || Lithium Aluminum Hydride-Cerium(III) Chloride
✍ Johnston, Jeffrey N. πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley & Sons, Ltd 🌐 English βš– 47 KB

Contains A Database Of Approximately 70,000 Reactions And 4000 Of The Most Frequently Consulted Reagents. Fully Searchable By Structure And Sub-structure, Reagent, Reaction Type, Experimental Conditions, And Keyword. Also Includes A Searchable Interface: Acronym Finder (an Interface For Scientific A

Cerium chloride-promoted nucleophilic ad
Cerium chloride-promoted nucleophilic addition of grignard reagents to ketones an efficient method for the synthesis of tertiary alcohols
✍ Tsuneo Imamoto; Nobuyuki Takiyama; Kimikazu Nakamura πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 248 KB

In the presence of anhydrous cerium(III1 chloride, Grignard reagents react with ketones to afford addition products in high yields, even though the substrates are susceptible to abnormal reactions with Grignard reagents alone. ## The reaction of Grignard reagents with carbonyl Sympounds is well-k

Chemoselective addition of grignard reag
Chemoselective addition of grignard reagents to alkoxycarbonylalkyl-N-imidazolium-N-methyl amides: Synthesis of 4-oxo and homologous esters
✍ MarΓ­a A. de las Heras; Juan J. Vaquero; JosΓ©L. GarcΓ­a-Navio; Julio Alvarez-Buill πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 165 KB

A method for the synthesis of 4-oxo and homologous esters is achieved by metalation of alkoxycarbonylalkyl-N-imidazolium-N-methyl amides with I equiv of LDA followed by highly ehemoseleetive addition of 1 equiv ofa Grignard reagent.