Synthesis of Unique Ceramides and Cerebr
β
Siliva MΓΌller; Richard R. Schmidt
π
Article
π
1993
π
John Wiley and Sons
π
German
β 984 KB
The sphingolipids la, b and 2a, b, which play important roles in epidermal barrier function, were synthesized by N-acylation of C,,-sphingosine 3 and I-0-glucosylated C,,-sphingosine 6, respectively, with w-acyloxy-substituted fatty acids 4 and 5 (Scheme 1 ) . These fatty acids were obtained from w-