Celacinnine, a novel macrocyclic spermidine alkaloid prototype
β Scribed by Kupchan, S. Morris; Hintz, Harold P. J.; Smith, Roger M.; Karim, Aziz; Cass, Malcolm W.; Court, William A.; Yatagai, Mitsuyoshi
- Book ID
- 121237480
- Publisher
- The Royal Society of Chemistry
- Year
- 1974
- Tongue
- English
- Weight
- 210 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0022-4936
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## Dedicated to Edgar Heilbronner on the occasion of his 80th birthday The macrocyclic lactam alkaloid (AE)-(2R\*,3R\*)-3-hydroxycelacinnine (1) derived from spermidine was synthesized via stereoselective epoxide-ring opening with magnesium azide and cesium carbonate promoted macrocyclization of t