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CD-spectra of N-2,4-dinitrophenyl(dnp) derivatives of aromatic amino acids: A simple method for determining their absolute configuration

✍ Scribed by Masao Kawai; Ukon Nagai; Motoko Katsumi

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 152 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)75011-8

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✦ Synopsis

In the course of systematic study of the chlroptlcal propertles of DNP-c(amino acids, we noted that CD-spectra of DNP-aromatlc amino acids show characterlstlc pattern, which 1s somewhat different from those of Na,Nw-dl-DNPamino aclds1)'2). They have lower intensity and their shorter wavelength band (ca.335 nm) lies shorter than that(ca.360 nm) of the di-DNP-amino acids.

The CD-spectra of common DNP-aromatic amino acids are reproduced in Fig. 3' C"2

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