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Cavity Ring-Down Spectroscopic Study of the Reactions of Br Atoms and BrO Radicals with Dimethyl sulfide

โœ Scribed by Nakano, Yukio; Goto, Masashi; Hashimoto, Satoshi; Kawasaki, Masahiro; Wallington, Timothy J.


Book ID
126899128
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
73 KB
Volume
105
Category
Article
ISSN
1089-5639

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Cavity ring-down study of BrO radicals:
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Reactions of CFSBr with H atoms and OH radicals have been studied a t room temperature a t 1-2 torr pressures in a discharge flow reactor coupled to an EPR spectrometer. The rate constant of the reaction H + CF3Br -CF3 + HBr (1) was found to be k l = (3.27 f 0.34) X cm:'/moleesec was determined for