Cavity Ring-Down Spectroscopic Study of the Reactions of Br Atoms and BrO Radicals with Dimethyl sulfide
โ Scribed by Nakano, Yukio; Goto, Masashi; Hashimoto, Satoshi; Kawasaki, Masahiro; Wallington, Timothy J.
- Book ID
- 126899128
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 73 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
Cavity ring-down (CRD) techniques were used to study the kinetics of the reaction of Br atoms with ozone in 1-205 Torr of either N 2 or O 2 , diluent at 298 K. By monitoring the rate of formation of BrO radicals, a value of k(Br ฯฉ O 3 ) ฯญ (1.2 ฯฎ 0.1) ฯซ 10 ฯช12 cm 3 molecule ฯช1 s ฯช1 was established th
Reactions of CFSBr with H atoms and OH radicals have been studied a t room temperature a t 1-2 torr pressures in a discharge flow reactor coupled to an EPR spectrometer. The rate constant of the reaction H + CF3Br -CF3 + HBr (1) was found to be k l = (3.27 f 0.34) X cm:'/moleesec was determined for