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Caveat in alkylative fragmentation of aldehyde tosylhydrazones of cyclic ethers

✍ Scribed by S. Chandrasekhar; M. Venkat Reddy; Mohamed Takhi

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 154 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01359-8

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✦ Synopsis

Tosylhydrazones of aldehydes at the a-position of cyclic ethers when exposed to carbon nucleophiles produce either ring opened alkylated olefinic alcohols and/or cyclic alkylated vinyl ethers, the ratio of which is dependent on nature of hydrazone and nucleophile used.

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