New entry to alicyclic amines via alkylative fragmentation of cyclic aminoaldehyde tosylhydrazones

✍ Scribed by S Chandrasekhar; M.Venkat Reddy; G Rajaiah

• Publisher: Elsevier Science
• Year: 2000
• Tongue: French
• Weight: 87 KB
• Volume: 41
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)01807-4

✦ Synopsis

Tosylhydrazones of cyclic aminoaldehydes when exposed to aromatic and aliphatic Grignard reagents produce ring-opened acyclic unsaturated primary carbamates and carbamate alcohols in good yields.