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Cationic rhodium hydrogenation catalysts containing chelating diphosphine ligands: effect of chelate ring size

✍ Scribed by Clark R. Landis; Jack Halpern


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
399 KB
Volume
250
Category
Article
ISSN
0022-328X

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Inverse two-dimensional 31P, 103Rh{1H}NM
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## Abstract A series of new and known Rh(I) complexes [Rh(R~2~P(CH~2~)__n__PR~2~)~2~]Y and [Rh(diene)(R~2~P(CH~2~)__n__PR~2~)]Y (R = Me, Et, Ph, C~6~F~5~, C~6~H~4~CF~3~; Y = Cl, ClO~4~, PF~4~, BF~4~, OSO~2~CF~3~; diene = norbornadiene, cyclooctadiene) were prepared and their ^103^Rh NMR spectra wer