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Cationic polymerization of 5-ethylidene-2-norbornene in the presence of boron compounds

✍ Scribed by Bermeshev, M. V.; Bulgakov, B. A.; Finkel’shtein, E. Sh.


Book ID
120221320
Publisher
Springer
Year
2013
Tongue
English
Weight
165 KB
Volume
449
Category
Article
ISSN
0012-5008

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✍ Frederik Blank; Harald Scherer; Christoph Janiak 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 438 KB

Oligomeric vinyl polynorbornene (2 to ∼12 monomer units) was obtained via hydrooligomerization of norbornene (NB) using the cationic palladium complexes [Pd(PPh 3 ) n (NCCH 3 ) 4-n ](BF 4 ) 2 [n = 0 (1), 3 (2)] at different hydrogen pressures. The vinyl polymerization of norbornene (NB) in the ionic