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Cationic polymerization of 1,3-pentadiene with (CH3)3SiCl/AlCl3

โœ Scribed by Y. X. Peng; W. M. Shi


Publisher
Springer
Year
1996
Tongue
English
Weight
226 KB
Volume
37
Category
Article
ISSN
0170-0839

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Cationic copolymerization of 1,3-pentadi
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Copolymerizations of 1,3-pentadiene (PD) with 1,3-cyclopentadiene (CPD) initiated by aluminium trichloride were carried out in toluene. The addition of CPD in the PD polymerization system does not affect the molecular weight but greatly increases the softening point of the polymer due to the introdu

Cationic Copolymerization of 1,3-Pentadi
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The cationic copolymerization of 1,3-pentadiene (PD) with isoprene (IP) initiated by AICl, was carried out in toluene. The microstructure of the copolymer chain was characterized by IR and 'H NMR. IP is incorporated in the copolymer chain mainly in cyclic segments. The PD-IP copolymer has a much hig