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Cationic Polymerization of 1,3-Pentadiene Initiated by Aluminum Chloride: Determination of the Various Side Reactions

✍ Scribed by Duchemin, Fabienne; Bennevault-Celton, Véronique; Cheradame, Hervé; Mérienne, Claude; Macedo, Anne

Book ID
120766179
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
281 KB
Volume
31
Category
Article
ISSN
0024-9297

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Demonstration of the Existence of Long-Lived Species in the Cationic Polymerization of 1,3-Pentadiene Initiated by Aluminium Trichloride in Non Polar Solvent
✍ Véronique Bennevault-Celton; Marilyn Delfour; Hervé Cheradame 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 221 KB

## Abstract **Summary:** A kinetic study of the polymerization of a mixture of 1,3‐pentadiene isomers initiated by AlCl~3~ was carried out in pentane at −10 and 20 °C. A second apparent monomer order was found mainly at room temperature and was explained by a complexation of propagating active cent