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Cationic polymerization initiated by onium ions

✍ Scribed by Qin Qin Zhu; Wolfram Schnabel


Book ID
108318491
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
624 KB
Volume
33
Category
Article
ISSN
0014-3057

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Cationic polymerization of styrene initi
✍ Takumi Taninaka; Yuji Minoura πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 378 KB

Cationic polymerization of styrene(St) initiated by phosphorus trichloride(PC13) in nitrobenzene was carried out at 30 Β°. The initial rate was proportional to [St] 2 and [PCl3]. The overall activation energy was about 10.4 kcal/mole. The rate and the degree of polymerization were enhanced with incre