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Cationic palladium complexes with ketophosphine and phosphino enolate ligands and their reactivity towards CC coupling reactions. Crystal structures of [PdMe{Ph2PCH2C(O)Ph}(PCy3)](PF6) and [Pd{Ph2PCH⋯C(⋯Ō)Ph}(SMe2)2](PF6)

✍ Scribed by Jacques Andrieu; Pierre Braunstein; Frédéric Naud; Richard D. Adams


Book ID
108346593
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
155 KB
Volume
601
Category
Article
ISSN
0022-328X

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Synthesis and Reactivity of [Ru(Cp*)(L)(
Enolate-Phosphane Ligands Providing a To
✍ Bernard Demerseman; Loïc Toupet 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB 👁 2 views

## Abstract The deprotonation under basic conditions of the keto‐phosphane ligand in complexes {Ru(Cp)[η^1^‐__P__‐Ph~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[η^2^‐__P__,__O__‐Ph~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp