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Cationic iridium(I) complexes of unsaturated aldehydes and their catalytic activities

✍ Scribed by Yang, Kyung Joon; Chin, Chong Shik


Book ID
126130346
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
287 KB
Volume
26
Category
Article
ISSN
0020-1669

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Catalytic hydrogen transfer activity of
✍ Mohammed Bikrani; Luz Fidalgo; MarΓ­a A. Garralda; Carlos Ubide πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 619 KB

## Cationic [Ir(COD)(LL)]+ species (LL = cr-diimines derived from biacetyl or glyoxal) in the presence of KOH are active catalysts in the homogeneous hydrogen transfer from isopropanol to acetophenone to give phenylethanol. The most active species is the cation containing biacetyloximehydrazone.