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Cationic Imido Alkylidene Complexes of Molybdenum Supported by β-Diketonate and β-Diketiminate Ligands

✍ Scribed by Tonzetich, Zachary J.; Jiang, Annie J.; Schrock, Richard R.; Müller, Peter


Book ID
127346408
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
148 KB
Volume
25
Category
Article
ISSN
0276-7333

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Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cat