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Cationic Crown Ether Complexes of Germanium(II)

✍ Scribed by Paul A. Rupar; Rajoshree Bandyopadhyay; Benjamin F. T. Cooper; Michael R. Stinchcombe; Paul J. Ragogna; Charles L. B. Macdonald; Kim M. Baines

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
319 KB
Volume
48
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Fit for a king: Cationic complexes of Ge^II^ can be prepared by using crown ethers to stabilize and protect the germanium center. Three different crown ethers were employed: [12]crown‐4 (see structure, Ge teal, O red, C gray), [15]crown‐5, and [18]crown‐6. The structures of the cationic complexes depend on the cavity size of the crown ether and on the substituent on germanium.magnified image

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Cationic Crown Ether Complexes of German
Cationic Crown Ether Complexes of Germanium(II)
✍ Paul A. Rupar; Rajoshree Bandyopadhyay; Benjamin F. T. Cooper; Michael R. Stinch 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB 👁 1 views

## Abstract **Die Krone muss passen**: Kationische Ge^II^‐Komplexe lassen sich mit Kronenethern zum Stabilisieren und Schützen des Germaniumzentrums herstellen. Drei verschiedene Kronenether wurden eingesetzt: [12]Krone‐4 (siehe Struktur, Ge türkis, O rot, C grau), [15]Krone‐5 und [18]Krone‐6. Die