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Cationic Copper(I) Complexes as Efficient Precatalysts for the Hydrosilylation of Carbonyl Compounds

✍ Scribed by Díez-González, Silvia; Scott, Natalie M.; Nolan, Steven P.


Book ID
111950500
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
136 KB
Volume
25
Category
Article
ISSN
0276-7333

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## Abstract Hydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas f