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Cationic Co(III)(salen)-catalyzed enantioselective Baeyer–Villiger oxidation of 3-arylcyclobutanones using hydrogen peroxide as a terminal oxidant

✍ Scribed by Tatsuya Uchida; Tsutomu Katsuki

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
72 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

A cationic Co(III)(salen) complex of cis-b-structure was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanone using hydrogen peroxide as a terminal oxidant. Good enantioselectivity up to 78% ee was achieved.

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