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Cation distributions on CoAl 2 O 4 and Co 2 AlO 4 spinels: pressure and temperature effects

✍ Scribed by Franco, R.; Tielens, F.; Calatayud, M.; Recio, J. M.

Book ID
120478057
Publisher
Taylor and Francis Group
Year
2008
Tongue
English
Weight
144 KB
Volume
28
Category
Article
ISSN
0895-7959

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Cation distribution and bond lengths in
Cation distribution and bond lengths in CoAl2O4 spinel
✍ Akihiko Nakatsuka; Yuya Ikeda; Yuzuru Yamasaki; Noriaki Nakayama; Tadato Mizota πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 162 KB

It is widely known that CoAl 2 O 4 , IV (Co 12x Al x ) VI [Co x Al 22x ]O 4 , is a largely normal spinel ð0 , x , 2=3Þ; but this cation distribution cannot be explained by the effects of cation size, electronegativity and ligand-field of Co 2þ . To examine the reason for this peculiar cation distrib