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High-temperature ligand field spectra and cation disorder and dynamics in spinels: CoAl2O4

✍ Scribed by K.D. Becker; F. Rau


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
608 KB
Volume
28-30
Category
Article
ISSN
0167-2738

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It is widely known that CoAl 2 O 4 , IV (Co 12x Al x ) VI [Co x Al 22x ]O 4 , is a largely normal spinel ð0 , x , 2=3Þ; but this cation distribution cannot be explained by the effects of cation size, electronegativity and ligand-field of Co 2þ . To examine the reason for this peculiar cation distrib