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Cation distribution in NixCd1−xMn2O4spinels

✍ Scribed by G. T. Bhandage; H. V. Keer

Publisher
Springer
Year
1987
Tongue
English
Weight
112 KB
Volume
6
Category
Article
ISSN
0261-8028

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Cation distribution and bond lengths in
Cation distribution and bond lengths in CoAl2O4 spinel
✍ Akihiko Nakatsuka; Yuya Ikeda; Yuzuru Yamasaki; Noriaki Nakayama; Tadato Mizota 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 162 KB

It is widely known that CoAl 2 O 4 , IV (Co 12x Al x ) VI [Co x Al 22x ]O 4 , is a largely normal spinel ð0 , x , 2=3Þ; but this cation distribution cannot be explained by the effects of cation size, electronegativity and ligand-field of Co 2þ . To examine the reason for this peculiar cation distrib