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Cation distribution in MgxNi1–xGa2O4 oxide spinels

✍ Scribed by Areán, C. Otero ;Trobajo-Fernandez, M. C.

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
328 KB
Volume
92
Category
Article
ISSN
0031-8965

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✍ Akihiko Nakatsuka; Yuya Ikeda; Yuzuru Yamasaki; Noriaki Nakayama; Tadato Mizota 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 162 KB

It is widely known that CoAl 2 O 4 , IV (Co 12x Al x ) VI [Co x Al 22x ]O 4 , is a largely normal spinel ð0 , x , 2=3Þ; but this cation distribution cannot be explained by the effects of cation size, electronegativity and ligand-field of Co 2þ . To examine the reason for this peculiar cation distrib