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Cation binding properties of photodimerizable polymers bearing benzodiglyme units

โœ Scribed by Masamitsu Shirai; Haruyuki Ishida; Makoto Tanaka


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
792 KB
Volume
26
Category
Article
ISSN
0887-6266

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Polymers, with differently sized crown ethers as alkali cation binding sites and photodimerizable cinnamoyl moieties in their side-chains, were prepared by the cationic copolymerization of the corresponding monomers. The form of the crown-cation complexes (l : l or 2 : l) was studied by measuring qu

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The cation-dependent decrease in fluorescence intensity of polyanions bearing 4'-acryloylbenzo-18-crown-6 (ACR18) or 4'-acryloylbenzo-15crown-5 (ACRIS) units was studied in water at 30ยฐC. The polyanions were prepared by the radical copolymerization of methacrylic acid, acrylic acid, or itaconic acid