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Alkali cation binding of polymers with different sized crown ethers and photodimerizable units

✍ Scribed by Masamitsu Shirai; Akihiko Ueda; Makoto Tanaka

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
670 KB
Volume
25
Category
Article
ISSN
0887-624X

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Polymers, with differently sized crown ethers as alkali cation binding sites and photodimerizable cinnamoyl moieties in their side-chains, were prepared by the cationic copolymerization of the corresponding monomers. The form of the crown-cation complexes (l : l or 2 : l) was studied by measuring qu

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## Abstract Five new cage‐annulated crown ethers, __i.e.__, 4a, 4b, 6b, 11a, and 11b, have been synthesized and their respective alkali metal picrate extraction profiles along with that of a previously synthesized host molecule, 6a, have been obtained. These results are compared with the correspond