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catena-Poly[tetra­aqua­manganese(II)-μ-4,4′-bipyridine] catena-poly[[diaqua­manganate(II)-di-μ-4-carboxy­phenoxy­acetato] dihydrate]

✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
183 KB
Volume
61
Category
Article
ISSN
1600-5368

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catena-Poly[[[diaqua­calcium(II)]-di-μ-3
✍ Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 212 KB

The Ca atom in the title compound, {[Ca(HO 2 CC 6 H 4 OCH 2 -CO 2 ) 2 (H 2 O) 2 ]Á2H 2 O} n , is eight-coordinate. The HO 2 CC 6 H 4 -OCH 2 CO 2 À monoanion binds in a chelating mode; it also functions as a bridge, linking adjacent Ca atoms into a zigzag chain. Hydrogen bonds link the chains into a