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catena-Poly[[dihydraziniummanganese(II)]-di-μ-sulfato-κ4O:O′] from synchrotron data

✍ Scribed by Srinivasan, Krishnan ;Govindarajan, Subbaiah ;Harrison, William T. A.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
411 KB
Volume
63
Category
Article
ISSN
1600-5368

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catena-Poly[[dihydrazinecadmium(II)]-di-
catena-Poly[[dihydrazinecadmium(II)]-di-μ-sulfato-κ4O:O′]
✍ Srinivasan, Krishnan ;Govindarajan, Subbaiah ;Harrison, William T. A. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 328 KB

The title compound, {[Cd(SO 4 ) 2 (N 2 H 5 ) 2 ]} n , contains fairly regular trans-CdN 2 O 4 octahedra. The Cd atoms (site symmetry 1) are bridged by pairs of sulfate groups into infinite chains. A network of N-HÁ Á ÁO hydrogen bonds, including a well defined trifurcated N-HÁ Á Á(O,O,O) link, compl