catena-Poly[[dihydrazinecadmium(II)]-di-μ-sulfato-κ4O:O′]

✍ Scribed by Srinivasan, Krishnan ;Govindarajan, Subbaiah ;Harrison, William T. A.

• Publisher: International Union of Crystallography
• Year: 2006
• Tongue: English
• Weight: 328 KB
• Volume: 62
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536806039511

✦ Synopsis

The title compound, {[Cd(SO 4 ) 2 (N 2 H 5 ) 2 ]} n , contains fairly regular trans-CdN 2 O 4 octahedra. The Cd atoms (site symmetry 1) are bridged by pairs of sulfate groups into infinite chains. A network of N-HÁ Á ÁO hydrogen bonds, including a well defined trifurcated N-HÁ Á Á(O,O,O) link, completes the structure, which is isostructural with its zinc(II) and chromium(II) analogues.