The title terbium coordination polymer, {[Tb 2 (C 8 H 4 O 4 ) 3 -(H 2 O) 2 ]} n , was obtained by the hydrothermal reaction of Tb(NO 3 ) 3 with benzene-1,3-dicarboxylic acid (1,3-BDC) in alkaline aqueous solution. In the asymmetric unit, there are two crystallographically independent Tb III ions: on
catena-Poly[diaquatris(μ3-biphenyl-2,2′-dicarboxylato)dierbium(III)]
✍ Scribed by Rui, Yang ;Yu-Qi, Liu ;Wen, Yang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 817 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title erbium coordination polymer, {[Er~2~(C~8~H~4~O~4~)~3~(H~2~O)~2~]·H~2~O}~__n__~, was obtained by the hydrothermal reaction of ErCl~3~ with benzene-1,3-dicarboxylic acid (1,3-BDC) in alkaline aqueous solution. Each of the two crystallographically independent Er^III^ ions is seven-coordinate
Poly [[diaquasamarium(III)]-l 3 -(biphenyl-4,4 0 0 0 -dicarboxylato)-l 3 -(4 0 0 0 -carboxylbiphenyl-4-carboxylato)]
Single-crystal X-ray study T = 293 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.025 wR factor = 0.062 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.