catena-Poly[[diaquadinitratozinc(II)]bis(μ-1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene)]
✍ Scribed by Paulin, Shakoya ;Kelly, Pierre ;Williams, Kenneth B. ;Goforth, Andrea M. ;Smith, Mark D. ;Peterson Jr, LeRoy ;zur Loye, Hans-Conrad
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 226 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The polymeric title complex, [Zn(NO 3 ) 2 (C 24 H 20 N 8 )(H 2 O) 2 ] n , features distorted ZnN 2 O 4 octahedra with each Zn II atom being located on an inversion center. Adjacent Zn ions are doubly bridged by two equivalent 1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene ligands to form linear chains.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.009 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.145 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the one-dimensional title polymer, [Cu(C 8 andL is 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene], Cu 2+ lies on a center of inversion. It is axially coordinated by two pyridyl N atoms from two different L ligands and equatorially coordinated by four O atoms from two chelating tta ligands. The ligan