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catena-Poly[[bis(α-thenoyltrifluoroacetonato)copper(II)]-μ-1,4-di-4-pyridyl-2,3-diazabuta-1,3-diene]

✍ Scribed by Perkins, William J. ;Maxwell, Tamara ;Goforth, Andrea M. ;Smith, Mark D. ;Peterson Jr, LeRoy ;zur Loye, Hans-Conrad

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 245 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805028631

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✦ Synopsis

In the one-dimensional title polymer, [Cu(C 8 andL is 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene], Cu 2+ lies on a center of inversion. It is axially coordinated by two pyridyl N atoms from two different L ligands and equatorially coordinated by four O atoms from two chelating tta ligands. The ligand L propagates the one-dimensional chain structure by serving as a bridging ligand between two Cu octahedra via Cu-N coordinate bonds.

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catena-Poly[[bis­(α-thenoyltrifluoro­acetonato)copper(II)]-μ-1,4-di-4-pyrid­yl-2,3-diazabuta-1,3-diene]

✦ Synopsis

catena-Poly[[bis(α-thenoyltrifluoroacetonato)copper(II)]-μ-1,4-di-4-pyridyl-2,3-diazabuta-1,3-diene]