catena-Poly[[bis(acetylacetonato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridyl-κ2N:N′]
✍ Scribed by Qian, Bao-Hua ;Ma, Wei-Xing ;Lu, Lu-De ;Yang, Xu-Jie ;Wang, Xin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 183 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The structure of the title complex, [Ni 2 (C 5 H 7 O 2 ) 4 (H 2 O) 2 ]Á-0.5H 2 O, is dimeric and corresponds to the trimeric structure of bis(acetylacetonato)nickel(II) in which one Ni(acac) 2 unit is replaced by two water molecules. The centrosymmetric molecule comprises two O-O edge-shared octahed
In the title coordination polymer, [Zn(C 8 H 6 NO 5 S) 2 -(C 10 H 8 N 2 )(H 2 O) 2 ] n , each Zn II ion is in a slightly distorted octahedral coordination environment, formed by two carboxylate O atoms from two (4-nitrophenylsulfinyl)acetate ligands, two N atoms from bipyridine ligands and two water
In the title coordination polymer, [Zn(C 8 H 6 ClO 3 S) 2 -(C 10 H 8 N 2 )(H 2 O) 2 ] n , the Zn II atom exists in an octahedral coordination environment that is formed by two carboxylate O atoms from two (4-chlorophenylsulfinyl)acetate ligands, two N atoms from two bipyridine ligands and two water