catena-Poly[[(2-methylimidazole)copper(II)]-μ-pyridine-2,6-dicarboxylato]
✍ Scribed by Xiang, Jing ;Mei, Ping ;Li, Qin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 167 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title hydrated 2,2 0 -bipyridine-6,6 0 -dicarboxylatecadmium(II) complex, {[Cd(C 12 H 2 N 2 O 4 )(H 2 O) 2 ]Á2H 2 O} n , crystallizes with eight oxygen-bridged monomer units in the unit cell. The divalent cadmium ion is seven-coordinate, and the coordination polyhedron can best be described as s
In the crystal structure of the title compound, [Cu(C 7 H 3 -NO 4 )(NH 3 ) 2 ], the Cu atom is coordinated in a squarepyramidal geometry by a pyridine-2,6-dicarboxylate ligand acting in an N,O,O 0 -tridentate chelating mode, and by two N atoms from two ammine ligands. A further long Cu-O bond involv
In the title polymer, [Cu(C 7 H 3 NO 4 )(H 2 O) 2 ] n , the Cu II ion is pentacoordinated and exhibits a distorted square-pyramidal environment formed by one N atom and two O atoms from pyridine-2,4-dicarboxylate ligands and two O atoms from coordinated water molecules. Each pyridine-2,4-dicarboxyla