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Catalyzed Vinylogous Mukaiyama Aldol Reactions with Controlled Enantio- and Diastereoselectivities

✍ Scribed by Marcus Frings; Iuliana Atodiresei; Jan Runsink; Gerhard Raabe; Carsten Bolm

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 198 KB
Volume: 15
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200802359

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## Abstract Vinylogous Mukaiyama‐type aldol reactions have been catalyzed by a combination of Cu(OTf)~2~ and readily available __C__~1~‐symmetric aminosulfoximines. After a fine‐tuning of the reaction conditions and an optimization of the modularly assembled ligand structure, high stereoselectiviti