CATALYZED NITRATION OF AMINES: I. DINITROXYDIETHYLNITRAMINE
โ Scribed by Herring, K. G.; Toombs, L. E.; Wright, George F; Chute, W. J.
- Book ID
- 120025822
- Publisher
- Canadian Science Publishing
- Year
- 1948
- Weight
- 448 KB
- Volume
- 26b
- Category
- Article
- ISSN
- 1923-4287
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๐ SIMILAR VOLUMES
The crystal structure of the title compound, [Ag-(C 14 H 15 N) 2 ]NO 3 , is the first reported structure of a silver complex with the dibenzylamine ligand. In the cation, the Ag I atom is linearly coordinated by two N atoms from dibenzylamine ligands, with Ag-N distances of 2.173 (3) and 2.178 (3) A
The copper(I) complex [Cu(CH 3 CN) 4 ]PF 6 catalyzes the allylic amination of alkenes by aryl hydroxylamine in fair to moderate yields. Unsymmetrical alkenes react with high regioselectivity with N-functionalization occuring at the less substituted vinylic carbon. Trapping experiments indicate that