Selective elimination of various hydrogen bonding functionalities in coal liquids is possible because there is a definite difference in catalyzed acylation of phenols and aromatic amines with trifluoroacetyl chloride (TFAC). Our study of model compound mixtures showed that when pyridine was added as
✦ LIBER ✦
Catalytic transfer hydrogenolysis of phenols and aromatic amines
✍ Scribed by A.S. Hay
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 90 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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## Abstract 1,2,4‐Triazin‐5(2__H__)‐ones 1 react as well with phenols, resorinol and its dimethyl ethers, as with dimethyland diethylaniline, yielding 6‐aryl‐1,6‐didydro‐1,2,4‐triazin‐5(2__H__)‐ones 2, 4–8, 12–15. Oxidation of the 1,6‐dihydroadducts 2a,b gives the corresponding 3‐aryl‐6‐hydroxyphen