Ammonium for-mate aided catalytic transfer hydrogenation has been employed in the cleavage, and concommitant deprotection, of the pentapeptide leucine enkephalin from the Merrifield peptide resin under ambient conditions of temperature and pressure in a neutral medium.
Applications of ammonium formate catalytic transfer hydrogenolysis--IV1: a facile method for dehalogenation of aromatic chlorocarbons
β Scribed by Mohmed K. Anwer; Arno F. Spatola
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 163 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Ammonium formate catalytic transfer hydrogenolysis, in the presence of palladium on carbon, has shown utility for the rapid dehalogenation of mono-or polychlorinated aromatic compounds in neutral media under ambient conditions of temperature and pressure.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Various aliphatic and aromatic nitro compounds were selectively and rapidly reduced to their corresponding amino derivatives in very good yield using anhydrous ammonium formate as a catalytic hydrogen transfer agent.