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Catalytic Transfer Hydrogenation of Ketones with KHCr(CO)5/HCO2H/Et3N Systems

✍ Scribed by Jean-Jacques Brunet; Remi Chauvin; Pascale Leglaye

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
187 KB
Volume
1999
Category
Article
ISSN
1434-1948

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✦ Synopsis

In the presence of a HCO 2 H/Et 3 N (1:1) mixture, KHCr(CO) 5 is also a stoichiometric reagent for the selective reduction of the carbon-carbon double bond of α,β-unsaturated ketones. is an efficient catalyst precursor for the transfer hydrogenation of ketones in THF at room temperature. KHCr(CO) 5 transfer from easy-to-handle hydrogen donors. Such re-

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