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Catalytic thiocyanation of aryldiazonium salts in the presence of copper salts

โœ Scribed by Irina P. Beletskaya; Alexander S. Sigeev; Alexander S. Peregudov; Pavel V. Petrovskii

Book ID
111730771
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
120 KB
Volume
16
Category
Article
ISSN
0959-9436

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The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X-ray analysis, the complexes show a unique coordination mode giving quinone-bridged dimers. The monocarbenepalladium(0) complexes allow