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Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts.

✍ Scribed by Kumaravel Selvakumar; Alexander Zapf; Anke Spannenberg; Matthias Beller

Publisher
John Wiley and Sons
Year
2003
Weight
199 KB
Volume
34
Category
Article
ISSN
0931-7597

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Synthesis of Monocarbenepalladium(0) Com
Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts
✍ Kumaravel Selvakumar; Alexander Zapf; Anke Spannenberg; Matthias Beller πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 149 KB πŸ‘ 1 views

The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X-ray analysis, the complexes show a unique coordination mode giving quinone-bridged dimers. The monocarbenepalladium(0) complexes allow