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Catalytic synthesis of isocyanates by carbonylation of nitro compounds in the presence of [Rh(CO)2Cl]2promoted by pyridine and pyridine hydrochloride

✍ Scribed by V. I. Manov-Yuvenskii; A. V. Smetanin; B. K. Nefedov


Book ID
112442864
Publisher
Springer
Year
1980
Tongue
English
Weight
417 KB
Volume
29
Category
Article
ISSN
1573-9171

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The regioselectivity of alkoxycarbonylation of 1-arylethanols catalysed by Pdracid systems is very sensitive to the nature of the counter anion of the acid: chloride anion favours branched products while tetrafluoroborate and sulfonates anions favour linear products, the latter ones enhancing also p