Catalytic Ring-Closing Olefin Metathesis of Sulfur-Containing Species: Heteroatom and Other Effects. -The ring-closure metathesis reaction of a variety of heteroatom-containing diallyl compounds in the presence of molybdenum (or ruthenium) alkylidenes is reported. The yields are strongly influenced
Catalytic ring-closing olefin metathesis of sulfur-containing species: Heteroatom and other effects
β Scribed by Young-Seok Shon; T. Randall Lee
- Book ID
- 104256445
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 194 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
This paper describes studies of the ring-closing metathesis of dialkyl sulfides and disulfides catalyzed by molybdenum and ruthenium alkylidenes. In general, the highest yields of ring-closed products were obtained using the molybdenum catalysts. Product yields were also strongly influenced by the substitution pattern about the double bonds: the yield of ring-closed products was found to decrease as the degree of substitution increased. These effects and other heteroatom effects are discussed.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v